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G. -D. Henkels, K. Kunstler, and K. Weinges, Annulen, 1975, 230. K. Weinges, P. -D. Henkels, Annulen, 1972, 759, 173. K. C. Joshi, L. Prakash, and L. B. Singh, Phytochemutry, 1075,14, 1441. A. Bianco, M. Guiso, C. Iavarone, and C. Trogolo, Gazzettu, 1975,105, 175. K. Weinges, P. -D. Henkels, Annulen, 1973, 566. 0. Sticher, A . Weisflog, U. Busch, and E. Rogenmoser, Schweiz. , 1974, 112, 523; Deut. , 1974, 114, 902. 0. Sticher, E. Rogenmoser. and A. Weisflog, Tetrahedron Letters, 1975, 291. M. Guiso, A .

Japan), 1975, 23. 279. *4h R. S. Becker, S. Berger, D . K. Dalling, D. M . Grant, and R. J. Pugmire, J. Amer. Chem. ,1974,96, 7008. 247 L. E. Brady, D. H. Williams, S. C. Traynor, and K . J . Crowley. Org. Mass Spectrometry, 1975,10, 1 16. 24x W. Cocker, K. J . Crowley, and S. G . S. Chen. , 1974,982. *4v S. Torii. K. Uneyama, and M. Isihara, Chem. Letters, 1975, 479. -Two new halogenated monoterpenoids are violacene (150) from Plocarniurn v i o l a c e ~ r na, ~1,4-dimethyl~~ 1-ethylcyclohexane which can be rationalized biosynthetically from the cyclization of an acyclic precursor via a bromonium ion, and plocamene B (15 l), again from Plocarniurn violaceurn, which may be the first member of a series of non-isoprenoid monoterpenoids from this species .

S. K. Rao, Chem. , 1975,707. T. Bosch, G. Kresze, and J. Winkler, Annalen, 1975, 1009. A. Siemieniuk, K. Piatkowski, and H. Kuczynski, Bull. Acad. polon. , Sir. Sci. , 1974,22. 1009. I . A. Southwell, Tetrahedron Letters, 1975, 1885. 240 Further catalytic reduction of mmenthadienes has been reported (Vol. 3, p. Vol. 3, p. -Esters of ferulol ( 145) are present in Scaevola Eobelia 243 and Cenolophium f i ~ c h e r(cf. i ~ Vol. ~ ~ 5 , p. '~~ ( 145) ( 146) The biogenetic-type asymmetric cyclization of citral gives (+)-a-cyclocitral of R, and not S, configuration as previously reported (Vol.

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